[Shortcut] Determine no. of paired/ unpaired e in a species e.g. Te+

 

 

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  • Determine total e count of the species.
  • If electron count is less than 18, it is faster to just write out the electronic configuration.
  • If electron count is more than 18, subtract e count by 18, 36 or 54; the largest number that will give you a positive result.
  • If the remainder is less than or equal to 10, fill them up in d orbitals. Ignore the quantum shell.
  • If the remainder is more than 10, subtract 10 from the remainder and fill up the leftover e in s and p orbitals. Ignore the quantum shell.

Example:

Determine the number of unpaired electrons in (a) Mn2+ (b) Cu+ (c) Se (d) Te+.

 

(a) Mn2+: 23e

e remaining = 23 – 18 = 5

Mn2+: […] nd5 → 5 unpaired  e

 

(b) Mo2+ : 40e

e remaining = 40 – 36 = 4

Mn2+: […] nd4 → 4 unpaired e

 

(c) Se: 35e

e remaining = 35 – 18 = 17 (> 10!)

e remaining = 17 – 10 = 7

Se: […] ns2np5 → 1 unpaired e

 

(d) Te+: 51e

Remaining electrons = 51 - 46 = 5 ns2np3: 3 unpaired electrons

e remaining = 51 – 36 = 15 (> 10!)

e remaining = 15 – 10 = 5

Te+: […] ns2np3 → 3 unpaired e